AIT Associated Repository of Academic Resources >
A.研究報告 >
A2 総合技術研究所研究報告 >
18号 >
Please use this identifier to cite or link to this item:
http://hdl.handle.net/11133/3142
|
Title: | 溶液プロセスによるデバイス化を目指した可溶性トリオキソトリアンギュレンの合成 |
Other Titles: | ヨウエキ プロセス ニヨル デバイスカ オ メザシタ カヨウセイ トリオキソトリアンギュレン ノ ゴウセイ Synthesis of Soluble Trioxotriangulene Derivatives toward Solution Processing Device Fabrication |
Authors: | 森田, 靖 村田, 剛志 MORITA, Yasushi MURATA, Tsuyoshi |
Issue Date: | 23-Sep-2016 |
Publisher: | 愛知工業大学 |
Abstract: | Novel trioxotriangulene (TOT) type stable neutral radicals with high solubility in organic solvents were synthesized with aim of new type liquid-phase secondary battery and solution-processed semiconductive devices such as photo voltaic cells. Benzene-rings having three alkoxy groups were introduced at the 2,6,10-positions of TOT skeleton via the cross-coupling reaction of the radical precursor of brominated TOT. These TOT derivatives were soluble to several organic solvents such as CH[2]Cl[2] and toluene, etc. The stereoelectronic effiects of substituent groups on the redox properties were investigated by the cyclic voltammetry. The electronic-spin structures were elucidated by the ESR spectra and sophisticated quantum chemical calculation. |
URI: | http://hdl.handle.net/11133/3142 |
Appears in Collections: | 18号
|
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
|