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http://hdl.handle.net/11133/249
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| Title: | 有機イソシアナートを一成分とするビニル重合 : 第一報 トルエンジイソシアナートによるメタクリル酸メチルの重合 |
| Other Titles: | ユウキ イソシアナート オ イチセイブン ト スル ビニル チョウゴウ : ダイイッポウ トルエンジイソシアナート ニヨル メタクリルサン メチル ノ チョウゴウ
Vinyl Polymerization by Organic Isocyanates Part 1. : Organic Isocyanate as Initiator for Methyl Methacrylate |
| Authors: | 岡本, 弘
稲垣, 慎二
尾之内, 千夫
OKAMOTO, Hiroshi
INAGAKI, Shinji
ONOUCHI, Yukio |
| Issue Date: | 30-Mar-1971 |
| Publisher: | 愛知工業大学 |
| Abstract: | It has been found that the binary mixture of toluene diisocyanate and triethylamine initiates the polymerization of methyl methacrylate effectively. The polymer showed relatively high melting point compared with the ordinary polymer prepared by radical initiator. The molecular weight determined by viscosity measurement was 10^6. The activation energy for this polymerization was found as 5.8Kcal/mole. A mechanism of the initiation reaction was suggested as radical. |
| URI: | http://hdl.handle.net/11133/249 |
| Appears in Collections: | 06号
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