|
AIT Associated Repository of Academic Resources >
A．研究報告 >
A2 総合技術研究所研究報告 >
14号 >
このアイテムの引用には次の識別子を使用してください:
http://hdl.handle.net/11133/2099
|
| タイトル: | Safety Improvement of Lithium Ion Batteries by Fluorine Compounds |
| 著者: | NAKAJIMA, T.
MATSUDA, Y.
OHZAWA, Y.
KOH, M.
YAMAUCHI, A.
KAGAWA, M.
AOYAMA, H. |
| 発行日: | 2012年9月27日 |
| 出版者: | 愛知工業大学 |
| 抄録: | Thermal stability，electrochemical oxidation stability and charge/discharge characteristics of natural graphite powder were investigated by mixing of five fluoro-carbonates with 1 mol/L LiCIO4-EC/DEC/PC (1:1:1 vol.). DSC study revealed that thermal stability of the electrolyte solution was improved by mixing of fluoro-carbonates by 10.0-33.3 vol.%. Electrochemical oxidation stability was also improved. Oxidation currents for Pt electrode were significantly decreased by mixing of fluoro-carbonates. In the fluoro-carbonate-mixed electrolyte solutions，e lectrochemical reduction of PC decreased with increasing concentration of fluoro-carbonate and current density. As a result，first coulombic efficiency for natural graphite electrode increased， that is，irreversible capacity decreased in the fluoro-carbonate-mixed solutions. |
| URI: | http://hdl.handle.net/11133/2099 |
| 出現コレクション: | 14号
|
このリポジトリに保管されているアイテムは、他に指定されている場合を除き、著作権により保護されています。
|
English
