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http://hdl.handle.net/11133/1668
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Title: | ハロゲン化芳香族化合物の光化学的脱ハロゲン化(3) : ハロゲン化N-置換フタロンイミド類の光化学的脱ハロゲン化 |
Other Titles: | Photochemical Dehalogenation of Halogenated Aromatic Compounds (3) : Photochemical Dehalogenation of Halogenated N-Substituted Phthalonimides |
Authors: | 立木, 次郎 松本, 裕伸 伊藤, 貴賢 TATSUGI, Jiro MATSUMOTO, Hironobu ITO, Takayoshi |
Issue Date: | 31-Aug-2007 |
Publisher: | 愛知工業大学 |
Abstract: | Photochemical dehalogenation of halogenated N-substituted phthalonimides in degassed solutions was investigated. Photochemical reactions of N-(chlorophenyl)phthalonimides in degassed 2-propanol gave 4-hydroxy-2-(chlorophenyl)-homophthalimides and 2-(chlorophenyl)homophthalimides together with N-(chlorophenyl)phthalimides. On the other hand, photochemical reactions of N-(bromophenyl)phthalommides in degassed 2-propanol afforded 4-hydroxy-2-(bromophenyl)homophthalimides and 2-(bromophenyl)homophthalimides. In the case of bromo substituted 2-phenyl-phthalonimides afforded also debrominated photoproducts, N-phenylhomophthalimides and N-phenyl-phthalonimdes as a minor products. |
URI: | http://hdl.handle.net/11133/1668 |
Appears in Collections: | 09号
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