DSpace DSpace 日本語

AIT Associated Repository of Academic Resources >
A.研究報告 >
A2 総合技術研究所研究報告 >
08号 >

Please use this identifier to cite or link to this item: http://hdl.handle.net/11133/1658

Title: ハロゲン化芳香族化合物の光化学的脱ハロゲン化(2) : ハロゲン化イサチン誘導体の光化学的脱ハロゲン化
Other Titles: Photochemical Dehalogenation of Halogenated Aromatic Compounds (2) : Photochemical Dehalogenation of Halogenated Isatin Derivatives
Authors: 立木, 次郎
土屋, 幸生
伊藤, 貴賢
ITO, Takayoshi
Issue Date: 1-Jul-2006
Publisher: 愛知工業大学
Abstract: Photochemical dehalogenation of halogenated 1-substituted 7-azaisatins in degassed solutions was investigated. Photochemical reactions of 1-alkyl-5-bromo-7-azaisatins in degassed 2-propanol gave 1-alkyl-7-azaistins and 1-alkyl-5-bromo-7-azaoxindoles. On the other hand, photochemical reactions of 1-alkyl-5-chloro-7-axaisatins in degassed 2-propanol afforded 1-alkyl-5-chloro-7-azaoxindoles which were followed by dechlorination to give 1-alkyl-7-azaoxindoles. Photoreaction of 1-(fluorobenzyl)-7-azaisatins gave selectively 1-(fluorobenzyl)-7-azaoxyindoles. Photochemical reactions of 1-(bromobenzyl)-7-azaisatins afforded 1-(bromobenzyl)-7-azaisatins which then reduced to 1-benzyl-7-azaoxindole. Photoreaction of 1-(chlorophenyl)-7-azaisatins afforded selectively 1-(chlorobenzyl)-7-azaoxindoles.
URI: http://hdl.handle.net/11133/1658
Appears in Collections:08号

Files in This Item:

File Description SizeFormat
総研8号(P19-24).pdf575.04 kBAdobe PDFView/Open

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.


Valid XHTML 1.0! DSpace Software Copyright © 2002-2010  Duraspace - Feedback